Concept:
Cannizzaro reaction is shown by aldehydes that do not have alpha hydrogen.
Step 1: Check condition.
Aldehyde must have no alpha hydrogen for Cannizzaro reaction.
Step 2: Check 2,2-dimethylbutanal.
In 2,2-dimethylbutanal, the alpha carbon is substituted and has no hydrogen.
Step 3: Conclusion.
Therefore, 2,2-dimethylbutanal undergoes Cannizzaro reaction.