Concept:
Actinoids show irregular electronic configurations due to small energy difference between \(5f\), \(6d\), and \(7s\) orbitals.
Step 1: Recall configuration of plutonium.
Plutonium has configuration approximately:
\[
[Rn]\,5f^6\,7s^2
\]
Step 2: Check 6d orbital.
There is no electron in the \(6d\) orbital in plutonium.
Step 3: Select answer.
Hence, the actinoid having no electron in \(6d\) orbital is:
\[
Pu
\]