Checking each pair.
Ortho and para nitrophenol are actually separated by steam distillation (the ortho isomer is steam-volatile due to intramolecular hydrogen bonding), not fractional distillation, so this pairing is wrong.
Crude oil is not separated by steam distillation either, so that pairing is also wrong.
The cereal-and-amla pairing does not correspond to a standard simple-distillation separation, so it is incorrect as well.
Crude oil is a mixture of hydrocarbons with closely spaced boiling points, and separating such a mixture is exactly what fractional distillation is designed for. So the correctly matched pair is option (D).