Question:

Which of the following statements is not correct?

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Methanol and ethanol are soluble in water, but higher alcohols like octanol are insoluble in water.
Updated On: Apr 22, 2026
  • All alcohols are miscible with water
  • Only lower alcohols are miscible with water
  • All alcohols are not poisonous
  • Methanol is poisonous
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The Correct Option is A

Solution and Explanation

Step 1: Analyzing the given statements.
- (1) All alcohols are miscible with water: This statement is incorrect. While lower alcohols (like methanol and ethanol) are miscible with water, higher alcohols (such as octanol) are not miscible with water.
- (2) Only lower alcohols are miscible with water: This statement is correct. The solubility decreases as the molecular weight of the alcohol increases.
- (3) All alcohols are not poisonous: This statement is correct. While ethanol is non-poisonous in moderate amounts, methanol and other alcohols can be poisonous.
- (4) Methanol is poisonous: This statement is correct. Methanol is indeed toxic and can cause blindness or death if ingested.

Step 2: Conclusion.

The correct answer is (1) All alcohols are miscible with water.
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