Step 1: Understanding the Question:
The question asks to identify the incorrect (wrong) statement among the four options regarding heat transfer mechanisms and thermal properties.
Step 2: Detailed Explanation:
• Statement A: Heat transfer in fluids (liquids and gases) primarily occurs via convection, where bulk fluid motion transports heat. This is a correct statement.
• Statement B: Fourier's Law of Heat Conduction states that heat flow rate ($Q = -k A \frac{dT}{dx}$) depends on the thermal conductivity ($k$), which is a characteristic property of the material of the body. This is a correct statement.
• Statement C: In solid metals, thermal energy is conducted primarily by free electrons and lattice vibrations (phonons).
As temperature increases, the thermal scattering of free electrons by the vibrating lattice ions increases significantly.
This increased scattering decreases the mean free path of the electrons, which generally causes the thermal conductivity ($k$) of most pure metals (like copper, aluminum) to decrease with a rise in temperature. Thus, Statement C is incorrect, making it the correct option for this "find the wrong statement" question.
• Statement D: The Logarithmic Mean Temperature Difference (LMTD) and Arithmetic Mean Temperature Difference (AMTD) are mathematically distinct:
\[ \text{LMTD} = \frac{\Delta T_1 - \Delta T_2}{\ln(\Delta T_1 / \Delta T_2)} \neq \frac{\Delta T_1 + \Delta T_2}{2} \]
LMTD is always less than AMTD. This is a correct statement.
Step 3: Final Answer:
The incorrect statement is (C) "The thermal conductivity of solid metals increases with rise in temperature".