Question:
Which of the following statement is incorrect with Kolbe’s electrolytic method?
Which of the following statement is incorrect with Kolbe’s electrolytic method?
Show Hint
In Kolbe's electrolytic method, decarboxylation leads to the formation of alkane radicals at the anode, not the formation of acetate free radicals.
Updated On: Apr 7, 2026
- It gives an alkane with even number of carbon atoms at the anode.
- At anode decarboxylation and formation of methyl radical occurs.
- Methane cannot be prepared by this method.
- At anode acetate ion accepts electrons to give acetate free radical.
- At cathode hydrogen gas is liberated.
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The Correct Option is D
Solution and Explanation
In Kolbe's electrolytic method, fatty acids undergo decarboxylation at the anode, leading to the formation of alkane radicals. The acetate ion does not accept electrons to form a free radical, so statement (D) is incorrect.
Thus, the correct answer is (D).
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