Question:

Which of the following reactions is a Wurtz - Fittig reaction?

Show Hint

Wurtz-Fittig: Aryl halide + Alkyl halide + Na → Alkylbenzene. Fittig: Aryl halide + Aryl halide + Na → Biaryl. Wurtz: Alkyl halide + Alkyl halide + Na → Alkane.
Updated On: Jun 4, 2026
  • \(C_6H_5Cl + CH_3Cl + 2Na \xrightarrow{\text{dry ether}} C_6H_5 - CH_3 + 2NaCl\)
  • \(C_2H_5Cl + CH_3Cl + 2Na \xrightarrow{\text{dry ether}} C_3H_8 + 2NaCl\)
  • \(2C_2H_5Cl + 2Na \xrightarrow{\text{dry ether}} C_2H_5 - C_2H_5 + 2NaCl\)
  • \(2C_6H_5Cl + 2Na \xrightarrow{\text{dry ether}} C_6H_5 - C_6H_5 + 2NaCl\)
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The Correct Option is A

Solution and Explanation

Step 1: Understanding the Question:
We need to identify the Wurtz-Fittig reaction among the given options.

Step 2: Key Formula or Approach:
Wurtz-Fittig reaction is a coupling between an aryl halide and an alkyl halide using sodium metal in dry ether to form an alkylarene.

Step 3: Detailed Explanation:
- (A): Aryl halide (C\(_6\)H\(_5\)Cl) + alkyl halide (CH\(_3\)Cl) → toluene – Wurtz-Fittig. - (B): Two alkyl halides → alkane – simple Wurtz reaction. - (C): Same alkyl halide – simple Wurtz. - (D): Two aryl halides – Fittig reaction.
Thus, only (A) is Wurtz-Fittig.

Step 4: Final Answer:
Option (A) is correct.
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