Step 1: Recall the definition of ester linkage.
An ester linkage has the functional group –COO– and is commonly found in polyesters formed by condensation of hydroxy acids. Step 2: Analyze each polymer. (A) PHBV: Poly(β-hydroxybutyrate-co-β-hydroxyvalerate) is a biodegradable polyester containing ester (–COO–) linkages — correct. (B) Orlon: It is polyacrylonitrile and contains –C≡N groups, not ester linkages. (C) Neoprene: It is polychloroprene and contains C–C and C–Cl bonds. (D) Buna–S: It is a copolymer of butadiene and styrene with C–C bonds. Step 3: Conclusion.
Only PHBV contains ester linkage among the given polymers.