Question:

Which of the following organic halogen compound has high reactivity towards \(S_N1\) mechanism?

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$S_{N}1$ Reactivity: Tertiary $>$ Secondary $>$ Primary.
Updated On: Apr 27, 2026
  • Chloroethane
  • Iodoethane
  • Chlorobenzene
  • 2-Chloropropane
  • Benzyl chloride
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The Correct Option is

Solution and Explanation

Step 1: Concept
$S_{N}1$ reactivity depends on the stability of the carbocation intermediate.

Step 2: Meaning

Benzyl carbocation is highly stable due to resonance with the benzene ring.

Step 3: Analysis

Primary and secondary alkyl halides are less reactive than benzylic halides in $S_{N}1$ conditions.

Step 4: Conclusion

Hence, the correct answer is Benzyl chloride.
Final Answer: (E)
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