Step 1: Identify the refining method described.
The process described is the Van Arkel–de Boer (iodide) process.
In this method, an impure metal is converted into a volatile iodide and then decomposed on a hot tungsten filament to obtain pure metal. Step 2: Recall metals purified by iodide process.
This method is used for refining metals like \(\mathrm{Zr}\) and \(\mathrm{Ti}\).
The metal iodide decomposes on the hot tungsten filament, depositing pure metal. Step 3: Analyze the given options. (A) Cu: Refined by electrolytic refining. (B) Zr: Correct — refined by iodide process using tungsten filament. (C) Al: Extracted by Hall–Héroult process. (D) Ni: Refined by Mond process. Step 4: Conclusion.
Zirconium is refined using a tungsten filament in the iodide process.