Question:

Which of the following is used to convert sodium chromate to sodium dichromate in the preparation of potassium dichromate?

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Sodium chromate is converted to sodium dichromate by heating with concentrated sulfuric acid, a common step in the preparation of potassium dichromate.
Updated On: Apr 18, 2026
  • \( \text{Na}_2\text{CO}_3 \)
  • \( \text{NaOH} \)
  • \( \text{KClO}_3 \)
  • \( \text{H}_2\text{SO}_4 \)
  • \( \text{H}_2\text{O}_2 \)
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The Correct Option is D

Solution and Explanation

Sodium chromate (\( \text{Na}_2\text{CrO}_4 \)) is converted to sodium dichromate (\( \text{Na}_2\text{Cr}_2\text{O}_7 \)) in the presence of concentrated sulfuric acid (\( \text{H}_2\text{SO}_4 \)). The chemical reaction is: \[ \text{Na}_2\text{CrO}_4 + \text{H}_2\text{SO}_4 \rightarrow \text{Na}_2\text{Cr}_2\text{O}_7 + \text{H}_2\text{O} \] Step 1: Conversion of sodium chromate to sodium dichromate.
The sulfuric acid acts as a dehydrating agent, converting sodium chromate to sodium dichromate. This reaction is essential in the preparation of potassium dichromate.
Step 2: Conclusion.
Therefore, the correct answer is (D) \( \text{H}_2\text{SO}_4 \), as sulfuric acid is used to convert sodium chromate to sodium dichromate.
Final Answer:} (D) \( \text{H}_2\text{SO}_4 \)
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