Question:

Which of the following is primary benzylic alcohol?

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Shortcut: $\text{Ph-CH}_2\text{OH}$ = primary benzylic alcohol (CH$_2$ next to benzene + OH)
Updated On: May 8, 2026
  • Fig A
  • Fig B
  • Fig C
  • Fig D
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The Correct Option is C

Solution and Explanation


Concept: A benzylic alcohol is one in which the \(-OH\) group is attached to a carbon directly bonded to a benzene ring. Primary benzylic alcohol means:
• The \(-OH\) is on a primary carbon (attached to only one carbon)
• That carbon is directly attached to benzene ring

Step 1: Analyze options

Option (A): OH on secondary carbon → Secondary benzylic alcohol $\times$ Option (B): OH on tertiary carbon → Tertiary benzylic alcohol $\times$ Option (C): Structure is \(\text{C}_6\text{H}_5-\text{CH}_2\text{OH}\)
• OH on primary carbon \checkmark
• Carbon directly attached to benzene \checkmark → Primary benzylic alcohol \checkmark Option (D): OH on secondary/branched carbon → Not primary $\times$ Conclusion: Only option (C) is a primary benzylic alcohol. Final Answer: Option (C)
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