Question:

Which of the following is obtained on dry distillation of equimolar mixture of calcium acetate and calcium propionate?

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When equimolar mixtures of calcium salts like acetate and propionate undergo dry distillation, ketones like ethyl methyl ketone are formed.
Updated On: Feb 18, 2026
  • Ethyl propyl ketone
  • Propionaldehyde
  • Acetaldehyde
  • Ethyl methyl ketone
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The Correct Option is D

Solution and Explanation

Step 1: Understanding the reaction.
When calcium acetate and calcium propionate undergo dry distillation, they form ketones and aldehydes. Ethyl methyl ketone is formed when the mixture is heated.
Step 2: Analyzing the options.
(A) Ethyl propyl ketone: This is not the product of this reaction.
(B) Propionaldehyde: This is also not the correct product.
(C) Acetaldehyde: Acetaldehyde is not formed from this reaction either.
(D) Ethyl methyl ketone: This is the correct product formed from dry distillation of calcium acetate and calcium propionate.
Step 3: Conclusion.
The correct answer is (D) Ethyl methyl ketone.
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