Concept:
In vector GIS, a line feature may also be called an arc, polyline, or edge.
A pixel is the smallest unit of raster data and is unrelated to vector line features.
Step 1: Recall GIS terminology.
\[
\boxed{
\begin{aligned}
\text{Arc} &\rightarrow \text{Line}\\
\text{Polyline} &\rightarrow \text{Line}\\
\text{Edge} &\rightarrow \text{Line}\\
\text{Pixel} &\rightarrow \text{Raster Cell}
\end{aligned}
}
\]
Step 2: Identify the incorrect synonym.
Hence,
\[
\boxed{\text{Pixel is not a synonym for a GIS line}.}
\]
Therefore, the correct option is
\[
\boxed{(D).}
\]