Concept:
Opacifiers are materials added to glazes or glasses to make them opaque by scattering light.
Step 1: In ceramic glaze, opacity is produced by adding special oxides.
Step 2: These oxides scatter light and reduce transparency.
Step 3: \(As_2O_3\), \(Sb_2O_3\), and \(ZnO\) can act as opacifying agents in ceramic/glass systems.
Step 4: \(Al_2O_3\) is mainly used as an alumina source. It improves viscosity, strength, and stability of glaze or ceramic body.
Step 5: It is not generally considered a standard opacifier among the given options.
Therefore, the compound which is not an opacifier is:
\[
\boxed{Al_2O_3}
\]