Question:

Which of the following has spinel crystal structure?

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Spinel structure has general formula \(AB_2O_4\). Magnesium aluminate \((MgAl_2O_4)\) is a typical spinel.
  • \(Fe_2O_3\)
  • \(MgAl_2O_4\)
  • \(CoO\)
  • \(Na_2O\)
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The Correct Option is B

Solution and Explanation

Spinel is an important crystal structure in ceramic materials. The general formula of a normal spinel is: \[ AB_2O_4. \] In this structure, divalent cations occupy one type of site and trivalent cations occupy another type of site. Magnesium aluminate has the formula: \[ MgAl_2O_4. \] Here: \[ Mg^{2+} \] acts as the divalent cation, and \[ Al^{3+} \] acts as the trivalent cation. Thus, magnesium aluminate exactly fits the spinel formula: \[ AB_2O_4. \] Therefore, the compound having spinel crystal structure is: \[ MgAl_2O_4. \]
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