Step 1: Recall reactivity of halogens.
Reactivity of halogens decreases down the group:
\[
\text{F}>\text{Cl}>\text{Br}>\text{I}
\]
Step 2: Reaction with hydrogen.
Fluorine reacts explosively with hydrogen even in the dark and at very low temperatures. Step 3: Conclusion.
Thus, fluorine combines with dihydrogen at the lowest temperature.