Step 1: Formula / Definition}
\[
\text{Cationic surfactant} \Rightarrow \text{positively charged head group}
\] Step 2: Calculation / Simplification}
Cetyl trimethyl ammonium bromide (\(\mathrm{C_{19}H_{42}BrN}\)) has \(\mathrm{R_4N^+}\) head group (cationic).
Sodium dodecyl sulphate is anionic. Sodium acetate and urea do not form micelles. Step 3: Final Answer
\[
\text{Cetyl trimethyl ammonium bromide}
\]