Question:

Which of the following enthalpy change is negative?

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Heat is released when a vapour condenses, so the enthalpy change of condensation is negative.
Updated On: Nov 12, 2026
  • Enthalpy of fusion
  • Enthalpy of condensation
  • Enthaly of vaporization
  • Enthalpy of sublimation
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The Correct Option is B

Solution and Explanation

Step 1: Understanding the Concept
Processes that absorb heat are endothermic with positive \(\Delta H\).
Processes that release heat are exothermic with negative \(\Delta H\).

Step 2: Analyse Each Option
Fusion, vaporisation and sublimation need heat to overcome intermolecular forces, so their \(\Delta H\) is positive.
Condensation is the reverse of vaporisation, so heat is released.

Step 3: Compare the options
Only the enthalpy of condensation is negative, which is option (B).

Final Answer:
The enthalpy of condensation is negative. \[ \boxed{\text{(B) }\text{Enthalpy of condensation}} \]
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