Step 1: Understanding the Concept:
Hydrogen bonding occurs when a hydrogen atom is covalently bonded to a highly electronegative atom (F, O, N) and is also attracted to an unshared pair on another electronegative atom.
Step 2: Detailed Explanation:
• HCl: H is bonded to Cl, but Cl is less electronegative and its size is large, making hydrogen bonding very weak in HCl. It does not form strong intermolecular H-bonds.
• C\(_2\)H\(_6\): H is bonded to C, not sufficiently electronegative.
• RCH\(_2\)CHO: H is bonded to C, not to O or N. The H in the aldehyde group is not directly bonded to O.
• RCH\(_2\)NHCH\(_3\): Contains a -NH- group where H is directly bonded to N. N is highly electronegative, allowing for strong hydrogen bonding between molecules.
Step 3: Final Answer:
RCH\(_2\)NHCH\(_3\) shows hydrogen bonding, which corresponds to option (D).