Step 1: Understanding the monomer in natural rubber.
Natural rubber is made from polymerizing 2-methyl-1,3-butadiene, also known as isoprene. This monomer undergoes addition polymerization to form polyisoprene, the polymer that makes up natural rubber.
Step 2: Analyzing the options.
(A) 1, 3-Butadiene: This is used in the production of synthetic rubber but is not the monomer in natural rubber.
(B) 2-Chloro-1,3-butadiene: This compound is not used in the production of natural rubber.
(C) Styrene: Styrene is used in the production of polystyrene, not natural rubber.
(D) 2-Methyl-1,3-butadiene: Correct — This is the monomer used in the production of natural rubber.
Step 3: Conclusion.
The correct monomer for natural rubber is (D) 2-Methyl-1,3-butadiene.