Question:
Which of the following compounds is obtained when alkyl halides reacted with silver nitrite?
Which of the following compounds is obtained when alkyl halides reacted with silver nitrite?
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Silver nitrite is covalent, so nitrogen donates its lone pair to the carbon.
Updated On: Nov 12, 2026
- Nitroalkanes
- Alkyl nitrite
- Alkyl isocyanide
- Alkyl cyanide
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The Correct Option is A
Solution and Explanation
Step 1: Understanding the Concept
The nitrite ion is an ambident nucleophile that can attack through nitrogen or oxygen.
Step 2: Role of silver nitrite
\(\text{AgNO}_2\) is mainly covalent, so the nitrogen lone pair is available and attacks the carbon of the alkyl halide.
Step 3: Product
\(R-X+\text{AgNO}_2\rightarrow R-\text{NO}_2+\text{AgX}\). This gives a nitroalkane.
Final Answer:
Alkyl halides give nitroalkanes with silver nitrite. \[ \boxed{\text{(A) }\text{Nitroalkanes}} \]
The nitrite ion is an ambident nucleophile that can attack through nitrogen or oxygen.
Step 2: Role of silver nitrite
\(\text{AgNO}_2\) is mainly covalent, so the nitrogen lone pair is available and attacks the carbon of the alkyl halide.
Step 3: Product
\(R-X+\text{AgNO}_2\rightarrow R-\text{NO}_2+\text{AgX}\). This gives a nitroalkane.
Final Answer:
Alkyl halides give nitroalkanes with silver nitrite. \[ \boxed{\text{(A) }\text{Nitroalkanes}} \]
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