Step 1: 2,2,4-Trimethylpentane (isooctane) contains:
• Primary carbons (1^∘) in methyl groups
• Secondary carbon (2^∘) in the chain
• Tertiary carbon (3^∘) at C-4
• Quaternary carbon (4^∘) at C-2
Step 2: Other options lack at least one type of carbon.