Question:

Which of the following compounds has a zero dipole moment?

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Symmetrical molecules like CO\(_2\), CCl\(_4\), and BeF\(_2\) often have zero dipole moments.
Updated On: Apr 16, 2026
  • CH\(_2\)Cl\(_2\)
  • NH\(_3\)
  • CH\(_4\)
  • PH\(_3\)
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The Correct Option is C

Solution and Explanation


Step 1:
Understanding the Concept:
A molecule has a zero dipole moment if the vector sum of all individual bond dipoles cancels out, which happens due to its symmetrical geometry.

Step 2:
Detailed Explanation:
CH\(_2\)Cl\(_2\): Tetrahedral but not symmetric (H and Cl differ). Net dipole moment is non-zero. • NH\(_3\): Trigonal pyramidal. The lone pair causes a net dipole moment. • CH\(_4\): Tetrahedral with identical C-H bonds. The vector sum of bond dipoles is zero. • PH\(_3\): Similar to NH\(_3\), has a net dipole moment.

Step 3:
Final Answer:
CH\(_4\) has a zero dipole moment, which corresponds to option (C).
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