Step 1: Understanding the Concept:
Starch has two parts: amylose and amylopectin. Both are built from \(\alpha\)-D-glucose units joined by glycosidic links.
Step 2: Details:
Amylose has \(\alpha\)-1,4 links in a long unbranched chain. Amylopectin also has \(\alpha\)-1,6 links at branch points.
Step 3: Other options:
\(\beta\)-D-glucose forms cellulose. L-glucose is not found in natural polysaccharides. So B, C and D are wrong.
Final Answer:
Starch is formed from \(\alpha\)-D-glucose, option (A).
\[ \boxed{\alpha\text{-D-glucose}} \]