Question:

Which of the following complexes is an outer orbital complex?

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Weak ligand \(\Rightarrow\) outer orbital complex.
Updated On: Apr 16, 2026
  • \([Co(NH_3)_6]^{3+}\)
  • \([Fe(CN)_6]^{4-}\)
  • \([Ni(NH_3)_6]^{2+}\)
  • \([Mn(CN)_6]^{4-}\)
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The Correct Option is C

Solution and Explanation

Concept: Outer orbital complexes use \(sp^3d^2\) hybridization (weak field ligands).

Step 1:
Check ligand strength.
\(NH_3\) = weak field → outer orbital.

Step 2:
Conclusion.
\([Ni(NH_3)_6]^{2+}\) is outer orbital.
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