Concept:
Metal oxides are commonly used as coloring agents in ceramic glazes. Different oxides produce different colors.
Step 1: Cobalt oxide is one of the strongest ceramic colorants.
Step 2: Cobalt oxide produces blue color in ceramic glaze.
\[
CoO \rightarrow \text{Blue color}
\]
Step 3: Nickel oxide generally gives grey, brown, or greenish shades depending on glaze composition.
Step 4: Manganese oxide generally gives brown, purple, or black shades.
Step 5: Zinc oxide is not mainly used to produce blue color.
Therefore, the coloring agent used to impart blue color in glaze is:
\[
\boxed{CoO}
\]