Concept:
Different allotropes of carbon have characteristic properties and applications based on their structure.
Step 1: Analyse each option.
• Graphite is used as an electrode because it is a good conductor of electricity. \checkmark
• Diamond is used for cutting and drilling due to its exceptional hardness. \checkmark
• Coke is widely used as a reducing agent in metallurgy. \checkmark
• Adsorption of poisonous gases is a property of activated charcoal, not carbon black. Carbon black is mainly used in tyres, inks and pigments. \(\times\)
Step 2: Final conclusion.
Hence, the incorrectly matched pair is
\[
\boxed{\text{Carbon black -- adsorbing poisonous gases}.}
\]
Therefore, the correct option is \(\boxed{(D)}\).