Step 1: Recall the facts
Physisorption is caused by weak Van der Waals forces and is exothermic.
Step 2: Check the options
(A) False. By Le Chatelier, raising temperature opposes an exothermic process.
(B) False. A larger surface area increases adsorption.
(C) False. Stronger Van der Waals forces increase adsorption.
(D) True.
Final Answer:
Physisorption decreases with temperature, option (D).
\[ \boxed{\text{(D)}} \]