Fumigants are pesticides that work in the form of toxic gases to control pests in stored grains, soil, warehouses, etc.
Let's analyze each compound:
- A. Aluminium phosphide
It releases phosphine gas on contact with moisture: $$\text{AlP} + 3H_2O \rightarrow Al(OH)_3 + PH_3$$ Phosphine gas \((PH_3)\) is highly toxic and used as a fumigant.
So, it is a fumigant. - B. Carbofuran
Carbofuran is a carbamate insecticide used mainly in soil and crops. It is not used in gaseous form.
So, it is not a fumigant. - C. Hydrogen cyanide
Hydrogen cyanide \((HCN)\) is a toxic gas historically used as a fumigant.
So, it is a fumigant. - D. Chlorpyriphos
Chlorpyriphos is an organophosphate insecticide used as spray or soil treatment, not as a fumigant gas.
So, it is not a fumigant.
Therefore, the substances that are not fumigants are:
$$\boxed{\text{B and D Only}}$$