Question:

Which of the following alkenes is most easily formed by dehydrohalogenation of alkyl halides?

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Zaitsev rule: more substituted alkene = more stable = major product.
Updated On: Apr 26, 2026
  • \(\text{R}_2\text{C = CH}_2\)
  • \(\text{RCH = CHR}\)
  • \(\text{R}_2\text{C = CHR}\)
  • \(\text{R}_2\text{C = CR}_2\)
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The Correct Option is D

Solution and Explanation

Concept:
According to Zaitsev's rule, during elimination reactions, the more substituted alkene is formed as the major product because it is more stable. Step 1: Understand stability of alkenes. Alkene stability increases with substitution: \[ \text{Tetra-substituted}>\text{Tri-substituted}>\text{Di-substituted}>\text{Mono-substituted} \]
Step 2: Analyze options.
  • (A) \(\text{R}_2\text{C = CH}_2\) → least substituted
  • (B) \(\text{RCH = CHR}\) → di-substituted
  • (C) \(\text{R}_2\text{C = CHR}\) → tri-substituted
  • (D) \(\text{R}_2\text{C = CR}_2\) → tetra-substituted (most stable) \checkmark

Step 3: Conclusion. \[ \text{Most substituted alkene forms most easily} \]
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