Step 1: Recall HVZ reaction condition.
Hell–Volhard–Zelinsky reaction occurs in carboxylic acids having at least one \(\alpha\)-hydrogen atom. Step 2: Analyze methanoic acid.
Methanoic acid (\(\mathrm{HCOOH}\)) has no \(\alpha\)-carbon and hence no \(\alpha\)-hydrogen. Step 3: Analyze other acids.
Ethanoic, propanoic, and butanoic acids contain \(\alpha\)-hydrogen atoms. Step 4: Conclusion.
Methanoic acid does not undergo HVZ reaction.