Step 1: Understanding the Concept
Thermosetting polymers become permanently hard on heating because extensive cross-links form between the chains. They cannot be remelted or remoulded.
Step 2: Bakelite
Bakelite, the phenol-formaldehyde resin, is a three-dimensional cross-linked network, so it is thermosetting.
Step 3: Other options
Polystyrene and PVC are thermoplastics that soften on heating. Nylon-6,6 is a fibre.
Final Answer:
Bakelite is a thermosetting polymer.
\[ \boxed{\text{(A) }\text{Bakelite}} \]