Concept:
Plants can take up various forms of nitrogen from the soil, but only specific inorganic ions are the primary sources for large-scale assimilation into plant proteins.
Step 1: Identifying Primary Inorganic Forms.
The two main inorganic forms of nitrogen that plants actively uptake and assimilate are Ammonium ($NH_4^+$) (B) and Nitrate ($NO_3^-$) (C).
Step 2: Eliminating Organic and Toxic Forms.
Amino acids (A) are organic forms of nitrogen, not inorganic. While plants can absorb them in small amounts, they are not the "standard" inorganic source. Nitrite ($NO_2^-$) (D) is an intermediate in the soil and is generally toxic to plants if it accumulates; plants typically do not assimilate large amounts of nitrogen directly from the soil in this form.
Step 3: Conclusion.
Therefore, the correct pair of inorganic ions used for plant nitrogen assimilation is $NH_4^+$ and $NO_3^-$, making option (2) the correct choice.