Step 1: Understanding the Concept
Electropositive character is the tendency to lose electrons and form cations. It increases down a group and decreases across a period.
Step 2: Compare the elements
Cs is a group 1 metal in period 6. Ba is a group 2 metal in the same period. Cu and Cr are transition metals with high ionisation enthalpies.
Step 3: Conclusion
Cs has the largest size and the lowest ionisation enthalpy of the four, so it is the most electropositive.
Final Answer:
Caesium is the most electropositive element.
\[ \boxed{\text{(B) }\text{Cs}} \]