Step 1: Understanding the Concept:
Alcohols and phenols are classified as mono-, di- or trihydric by the number of \(-\text{OH}\) groups.
Step 2: Count the OH Groups:
Crotonyl (crotyl) alcohol: \(\text{CH}_3\text{CH}=\text{CHCH}_2\text{OH}\), one OH.
Ethylene glycol: \(\text{HOCH}_2\text{CH}_2\text{OH}\), two OH.
Pyrogallol: benzene-1,2,3-triol, three OH.
Hydroquinone: benzene-1,4-diol, two OH.
Step 3: Conclusion:
Only crotonyl alcohol is monohydric, so (A) is correct.
Final Answer:
Crotonyl alcohol has a single OH group, option (A).
\[ \boxed{\text{(A) Crotonyl alcohol}} \]