Step 1: Concept
Work done by a gas during expansion is given by $W = -P_{ext}\Delta V$.
Step 2: Meaning
"Free expansion" refers to the expansion of a gas into a vacuum.
Step 3: Analysis
In a vacuum, the external pressure ($P_{ext}$) is zero.
Since $W = -P_{ext} \times \Delta V$, if $P_{ext} = 0$, then $W = 0 \times \Delta V = 0$.
In isobaric, adiabatic, and isothermal processes (unless in a vacuum), $P_{ext}$ is non-zero, resulting in non-zero work.
Step 4: Conclusion
Free expansion always involves zero work done.
Final Answer: (D)