Step 1: Understanding the Concept
A polyester is formed by condensation of hydroxy acids or of diols with dicarboxylic acids, so the chain contains ester groups.
Step 2: Check the Options
PHBV (poly-\(\beta\)-hydroxybutyrate-co-\(\beta\)-hydroxyvalerate) is a copolyester of 3-hydroxybutanoic acid and 3-hydroxypentanoic acid.
Urea formaldehyde is a thermosetting amino resin, thermocol is expanded polystyrene and polyacrylonitrile is an addition polymer (acrylic fibre).
Step 3: Compare the options
Only PHBV is a polyester.
Final Answer:
PHBV is the polyester.
\[ \boxed{\text{(A) }\text{PHBV}} \]