Step 1: Concept
For a homologous series, boiling point increases with molecular mass.
Step 2: Meaning
Higher surface area and Van der Waals forces lead to higher boiling points.
Step 3: Analysis
- Methanal ($C_{1}$), Ethanol ($C_{2}$), Propanol ($C_{3}$), Butanol ($C_{4}$).
- Methanol has the smallest carbon chain and lowest molecular weight.
Step 4: Conclusion
Hence, Methanol has the lowest boiling point.
Final Answer: (D)