Step 1: The iodoform test is positive for compounds with a CH3-CO- group or a CH3-CH(OH)- group.
Step 2: Acetaldehyde, acetone, and acetophenone all have this CH3-CO- arrangement.
Step 3: Propanal, CH3-CH2-CHO, has an ethyl group on the carbonyl, not a methyl group, so it gives a negative test.
\[\boxed{\text{Propanal}}\]