Step 1: Understanding the Raschig method.
In the Raschig method for phenol preparation, a catalyst like calcium phosphate is used to catalyze the reaction between benzene and chlorine to form phenol. Step 2: Analyzing the options. (A) Calcium Sulphate: Incorrect. Calcium sulphate is not used in the Raschig method for phenol preparation. (B) Calcium phosphate: Correct. Calcium phosphate is the catalyst used in the Raschig method for phenol preparation. (C) Calcium chloride: Incorrect. Calcium chloride is not used in this process. (D) Calcium carbonate: Incorrect. Calcium carbonate is not involved in this method. Step 3: Conclusion.
The correct answer is (B) Calcium phosphate.