Step 1: Understanding the Concept
Aldehydes are polar and have dipole-dipole attractions.
Within a homologous series, van der Waals forces increase with size, so boiling point rises with chain length.
Step 2: Carbon count
Ethanal has 2 carbons, propanal 3, pentanal 5 and hexanal 6.
Step 3: Conclusion
Hexanal has the longest chain, so it has the highest boiling point.
Final Answer:
Hexanal has the highest boiling point.
\[ \boxed{\text{(D) }\text{Hexanal}} \]