Question:

Which among the following compounds has highest boiling point?

Show Hint

Within a homologous series, boiling point increases with molecular mass and chain length.
Updated On: Nov 13, 2026
  • Propanal
  • Ethanal
  • Pentanal
  • Hexanal
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The Correct Option is D

Solution and Explanation

Step 1: Understanding the Concept
Aldehydes are polar and have dipole-dipole attractions.
Within a homologous series, van der Waals forces increase with size, so boiling point rises with chain length.

Step 2: Carbon count
Ethanal has 2 carbons, propanal 3, pentanal 5 and hexanal 6.

Step 3: Conclusion
Hexanal has the longest chain, so it has the highest boiling point.

Final Answer:
Hexanal has the highest boiling point. \[ \boxed{\text{(D) }\text{Hexanal}} \]
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