Step 1: Concept
Amino acids have the general formula $R-\text{CH}(\text{NH}_2)\text{COOH}$. The $R$ group is the side chain.
Step 2: Identification
- Glycine: $R = \text{H}$
- Alanine: $R = \text{CH}_3$
- Valine: $R = \text{CH}(\text{CH}_3)_2$
- Serine: $R = \text{CH}_2\text{OH}$
Step 3: Conclusion
Alanine has a methyl group ($-\text{CH}_3$) as its side chain.
Final Answer: (B)