Question:

When methanamine is treated with benzoyl chloride, the major product is

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Acid chloride + amine → amide formation (Schotten-Baumann reaction).
Updated On: May 8, 2026
  • N-phenylethanamide
  • N-methylbenzamide
  • benzanilide
  • acetophenone
  • N-ethylethanamide
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The Correct Option is B

Solution and Explanation

Concept: Amines react with acid chlorides to form amides via Schotten-Baumann reaction.

Step 1: Identify reactants.

• Methanamine: \(CH_3NH_2\)
• Benzoyl chloride: \(C_6H_5COCl\)

Step 2: Reaction mechanism.

• Nitrogen attacks carbonyl carbon
• Chlorine leaves
• Amide is formed

Step 3: Write reaction.
\[ CH_3NH_2 + C_6H_5COCl \rightarrow C_6H_5CONHCH_3 + HCl \]

Step 4: Identify product.
Product is: \[ \text{N-methylbenzamide} \]

Step 5: Match with options.
Correct option is (B). Final Conclusion: \[ \boxed{\text{N-methylbenzamide}} \]
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