Question:

What type of isomerism is exhibited by neopentane?

Show Hint

Neopentane is one of the three isomers of C$_5$H$_{12}$, which differ in carbon skeleton.
Updated On: Oct 3, 2026
  • position
  • chain
  • geometrical
  • tautomerism
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The Correct Option is B

Solution and Explanation

Step 1: Identify the compound
Neopentane is 2,2-dimethylpropane, C\(_5\)H\(_{12}\).

Step 2: Find the isomer relation
C\(_5\)H\(_{12}\) has three structures: n-pentane, isopentane and neopentane. They differ only in the chain of carbon atoms, so this is chain isomerism.

Step 3: Others
Position isomerism needs a movable substituent or double bond. Geometrical isomerism needs a double bond or ring. Tautomerism needs a labile hydrogen with a carbonyl-like group. None applies.

Final Answer:
Neopentane shows chain isomerism, option (B). \[ \boxed{\text{(B) chain}} \]
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