Step 1: Identify the compound
Neopentane is 2,2-dimethylpropane, C\(_5\)H\(_{12}\).
Step 2: Find the isomer relation
C\(_5\)H\(_{12}\) has three structures: n-pentane, isopentane and neopentane. They differ only in the chain of carbon atoms, so this is chain isomerism.
Step 3: Others
Position isomerism needs a movable substituent or double bond. Geometrical isomerism needs a double bond or ring. Tautomerism needs a labile hydrogen with a carbonyl-like group. None applies.
Final Answer:
Neopentane shows chain isomerism, option (B).
\[ \boxed{\text{(B) chain}} \]