Concept:
The Van't Hoff factor (\(i\)) represents the number of particles into which a substance dissociates in solution. It is used in colligative properties such as boiling point elevation, freezing point depression, and osmotic pressure.
Step 1: Understanding non-electrolytes.
A non-electrolyte is a substance that does not dissociate into ions when dissolved in water. It remains as whole molecules in solution.
Step 2: Value of Van't Hoff factor.
Since a non-electrolyte does not dissociate, the number of particles in solution remains the same as the number of molecules dissolved.
Thus,
\[
i = 1
\]
Step 3: Conclusion.
Therefore, the Van't Hoff factor for a non-electrolyte is \(\mathbf{i = 1}\).