Step 1: Use the general formula of alkanes.
Alkanes have the general formula \( \mathrm{C_nH_{2n+2}} \). Step 2: Express molar mass in terms of \(n\).
Molar mass \(= 12n + (2n+2) = 14n + 2 \).
Given molar mass \(= 100\).
\[
14n + 2 = 100
\]
\[
14n = 98 \Rightarrow n = 7
\] Step 3: Identify the alkane.
For \(n = 7\), the alkane is heptane \(\mathrm{C_7H_{16}}\). Step 4: Match with petroleum fractions.
Heptane is a major constituent of petrol (gasoline). Step 5: Conclusion.
The given alkane belongs to the petrol fraction.