Question:

What is the product formed when a primary alcohol undergoes catalytic dehydrogenation by passing its vapor over heated copper at \(573\) K ?

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Primary alcohols give aldehydes on dehydrogenation over copper at 573 K.
Updated On: Nov 12, 2026
  • Ketone
  • Aldehyde
  • Alkene
  • Ether
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The Correct Option is B

Solution and Explanation

Step 1: Understanding the Concept
When alcohol vapour passes over heated copper at \(573\) K, it loses hydrogen (dehydrogenation).

Step 2: Apply to a primary alcohol
\(\text{RCH}_{2}\text{OH}\xrightarrow{\text{Cu},\,573\,\text{K}}\text{RCHO}+\text{H}_{2}\)
The product is an aldehyde.

Step 3: Compare with other alcohols
Secondary alcohols give ketones, and tertiary alcohols give alkenes by dehydration.

Final Answer:
A primary alcohol gives an aldehyde. \[ \boxed{\text{(B) }\text{Aldehyde}} \]
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