Concept:
Portland cement mainly contains lime \((CaO)\), silica \((SiO_2)\), alumina \((Al_2O_3)\), and iron oxide \((Fe_2O_3)\).
Step 1: Lime is the major oxide present in Portland cement.
Step 2: Lime combines with silica, alumina, and iron oxide to form clinker phases.
Step 3: The usual percentage of \(CaO\) in ordinary Portland cement is approximately:
\[
60-65\%
\]
Step 4: Therefore, the correct range is:
\[
\boxed{60-65}
\]