Step 1: Write molecular formula of urea.
Urea = \(\text{CO(NH}_2)_2\).
Step 2: Calculate mass of carbon.
Mass of carbon in one mole of urea = \(12\,\text{g}\).
Step 3: Calculate mass percentage.
\[
%\text{ of C} = \frac{12}{60} \times 100 = 20.0%
\]
Step 4: Conclusion.
Thus, the mass percentage of carbon in urea is \(20.0%\).